The influence of poorly interconnected fault zone flow paths on spring geochemistry

Thermal springs commonly occur along faults because of the enhanced vertical permeability afforded by fracture zones. Field and laboratory studies of fault zone materials document substantial heterogeneities in fracture permeabilities. Modeling and field studies of springs suggest that spatial variations in permeability strongly influence spring locations, discharge rates and temperatures. The impact of heterogeneous permeability on spring geochemistry, however, is poorly documented. We present stable isotope and water chemistry data from a series of closely spaced thermal springs associated with the Hayward Fault, California. We suggest that substantial spatial variations observed in dO and chloride values reflect subsurface fluid transport through a poorly connected fracture network in which mixing of subsurface waters remains limited. Our measurements provide insight into the effect of fracture zone heterogeneities on spring geochemistry, offer an additional tool to intuit the nature of tectonically induced changes in fault zone plumbing, and highlight the need to consider local variations when characterizing fracture zone fluid geochemistry from spring systems with multiple discharge sites.